I go to Database | Administer | Tablespaces (or access it from the Schema Browser). In the Space tab of the View Tablespaces window, I can double click on a tablespace name; however, at the Alter Tablespace pop up window in Toad 10, double clicking on any data file no longer opens the Datafile Definition window.
WORKAROUND:
In Toad 10 you have to click on the Alter Datafile icon.
STATUS:
Enhancement request has been submitted to Development for consideration in a future release of Toad for Oracle.
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